Addition of Amino Group to C-C Double Bond
نویسندگان
چکیده
منابع مشابه
NBS mediated nitriles synthesis through C=C double bond cleavage.
An NBS mediated nitriles synthesis through C=C double bond cleavage has been developed. TMSN3 was employed as the nitrogen source for this Cu(OAc)2 promoted nitrogenation reaction. This transformation has a relatively high regio-selectivity to form aromatic nitriles.
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The Longuet-Higgins phase change theorem is used to show that, in certain photochemical reactions, a single product is formed via a conical intersection. The cis-trans isomerization around the double bond in the formaldiminium cation and vinylamine are shown to be possible examples. This situation is expected to hold when the reactant can be converted to the product via two distinct elementary ...
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ژورنال
عنوان ژورنال: Nippon kagaku zassi
سال: 1950
ISSN: 0369-5387,2185-0917
DOI: 10.1246/nikkashi1948.71.515